The critical angle is given by sin ic = n2 / n1, where n1 and n2 are the indices of refraction for the media.
Using the formula sin ic = n2 / n1 for the critical angle for a liquid-air surface, we can calculate the index of refraction of the liquid.47.7° = sinic = n2 / n1, where n1 is the index of refraction of air, which is 1.00. The index of refraction of the liquid is therefore 1.33.
When light travels from a medium with a high refractive index (n1) to a medium with a low refractive index (n2), total internal reflection occurs if the angle of incidence is greater than the critical angle (ic).
The critical angle (ic) can be calculated using the formula sin ic = n2 / n1, where n1 and n2 are the indices of refraction of the media. The angle of incidence that causes total internal reflection is the critical angle.
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What experimental evidence led Rutherford to conclude the following: (a) The nucleus of the atom contains most of the atomic mass. The nucleus of the atom contains most of the mass since only a collision with a very dense, massive object would cause an alpha particle to be the source. (b) The nucleus of the atom is positively charged. The positive alpha particles their initial flight indicating that the nucleus of the atom is also positively charged. (c) The atom consists of mostly empty space. Most alpha particles pass through the gold foil leading to the conclusion that the atom is mostly empty space.
Answer:
See Explanation
Explanation:
The experiment of Ernest Rutherford involved the bombardment of a thin gold foil with alpha particles from a radioactive source. A zinc sulphide screen was used to follow the movement of the alpha particles.
It was discovered that most of the alpha particles followed a straight path through the gold foil. Some of them were scattered through large angles and few were even scattered in the backward direction.
Since alpha particles were heavier than electrons, they must have been deflected by very strong forces.
These experimental evidences led to the conclusions stated in the question.
how many moles is 62 G of oxygen gas
Answer:
There are 2 moles of oxygen molecules; there are 4 moles of oxygen atoms.
Explanation:
Calculate the expected initial pH for Buffer 1 and for Buffer 2. Buffer 1: Add 15 mL of 0.10 M HC2H2O2 to a 25 mL volumetric flask using the syringe. Rinse the syringe with water. Add 10 mL of 0.10 NaC2H2O2 to the same volumetric flask using the syringe. Buffer 2: Add 10 mL of 0.50 M HC2H302 to a 25 mL volumetric flask using the syringe. Rinse the syringe with water. Add 15 mL of 0.50 M NaC2H2O2 to the same volumetric flask using the syringe.
The expected initial pH for Buffer 1 and Buffer 2 is 4.54 and 4.94 respectively.
Buffer 1 is made of Acetate buffer and buffer 2 is made of Acetate buffer as well. We know the volume and concentration of the acid and salt in both buffers. The expected initial pH of Buffer 1 and Buffer 2 can be calculated using the Henderson-Hasselbalch equation. The Henderson-Hasselbalch equation is given as: pH = pKa + log {[A-]/[HA]}where[A-] is the concentration of the salt (NaC2H2O2),[HA] is the concentration of the acid (HC2H2O2),pKa is the acid dissociation constant of the acid (HC2H2O2).
Buffer 1: HC2H2O2 + H2O ⇔ C2H2O2- + H3O+No. of moles of HC2H2O2 = 0.10 M x 0.015 L = 0.0015 mol. No. of moles of NaC2H2O2 = 0.10 M x 0.01 L = 0.001 mol. Total volume = 0.015 L + 0.01 L = 0.025 L[HA] = 0.0015 mol/ 0.025 L = 0.06 M[A-] = 0.001 mol/0.025 L = 0.04 M. The pKa for HC2H2O2 is 4.76pH = 4.76 + log {[0.04]/[0.06]}= 4.76 - 0.22 = 4.54Thus, the expected initial pH for Buffer 1 is 4.54.
Buffer 2: HC2H302 + H2O ⇔ C2H3O2- + H3O+No. of moles of HC2H302 = 0.50 M x 0.01 L = 0.005 molNo. of moles of NaC2H2O2 = 0.50 M x 0.015 L = 0.0075 mol. Total volume = 0.01 L + 0.015 L = 0.025 L[HA] = 0.005 mol/ 0.025 L = 0.20 M[A-] = 0.0075 mol/0.025 L = 0.30 M. The pKa for HC2H302 is 4.76pH = 4.76 + log {[0.30]/[0.20]}= 4.76 + 0.18 = 4.94Thus, the expected initial pH for Buffer 2 is 4.94.
Therefore, the expected initial pH for Buffer 1 and Buffer 2 is 4.54 and 4.94 respectively.
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A sheet of glass has n_red =1.52 and n_violet =1.55. A narrow beam of white light is incident on the glass at 28.0 (degrees)
What is the angular spread of the light inside the glass?
Please show work I am down to my last try
I will rate 5 stars for all the work and hopefully correct answer
The angular spread of the light inside the glass is 132.4° for red light and 132.2° for violet light.
Given data: Red light n_red =1.52Violet light n_violet =1.55. Incident angle i = 28°To find: The angular spread of the light inside the glass.
Solution: The angle of incidence i = 28°The angle of refraction r can be calculated using Snell's law:µ1 sin i = µ2 sin where µ1 is the refractive index of the incident medium (air), µ2 is the refractive index of the refracting medium (glass), i is the angle of incidence, and r is the angle of refraction. For red light,µ1 = 1.0003 and µ2 = 1.52For violet light,µ1 = 1.0003 and µ2 = 1.55.
The angle of refraction can be calculated as follows: Red light: sin r = µ1/µ2 sin i= 1.0003/1.52 × sin 28°= 0.3736r = sin–1 (0.3736) = 22.31°Violet light: sin r = µ1/µ2 sin i= 1.0003/1.55 × sin 28°= 0.3863r = sin–1 (0.3863) = 22.93°The angle of deviation δ for a prism is given by:δ = (µ − 1)A. where µ is the refractive index of the prism and A is the angle of the prism. From the geometry of the prism, the angle of deviation can be related to the angle of incidence and the angle of refraction by the formula:δ = I + r – A where A is the apex angle of the prism.
Since the angle of deviation for red and violet light is the same, we can equate the two expressions for δ to obtain: I + r – A = i’ + r’ – A where i’ and r’ are the angles of incidence and refraction for violet light. Subtracting I + r = i’ + r’ from the above equation, we get: A = (i’ – i) + (r’ – r)Let the angular spread of the light inside the glass be θ. Then,θ = A/2= [(i’ – i) + (r’ – r)]/2For red light: i’ = 180° – 22.31° = 157.69°r’ = 180° – sin–1 (sin r/µ1) = 180° – sin–1 (0.2617/1.0003) = 157.45°θ = [(157.69° – 28.00°) + (157.45° – 22.31°)]/2= 132.41°For violet light: i’ = 180° – 22.93° = 157.07°r’ = 180° – sin–1 (sin r/µ1) = 180° – sin–1 (0.2491/1.0003) = 157.24°θ = [(157.07° – 28.00°) + (157.24° – 22.93°)]/2= 132.19°
Therefore, the angular spread of the light inside the glass is 132.4° for red light and 132.2° for violet light.
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This is my 6th time posting this questions. please not bots or links
and please *explain* the answer and steps
I really need help understanding this.
describe the process to determine the limiting reactant in the example listed below:
Given 3.4 grams of x element with a molar mass of 24 g/mol and 4.2 grams of y element with a molar mass of 35 g/mol. How much of compound xy2 can be generated?
x + 2y -> xy2
The amount of the compound [tex]XY_2[/tex] that can be generated would be 11.28 grams
Stoichiometric calculationFrom the equation of the reaction, the mole ratio of X and Y is 1:1.
Mole of 3.5 grams of X = 3.4/24 = 0.1417 moles
Mole of 4.2 grams of Y = 4.2/35 = 0.12 moles
Thus, Y is the limiting reactant because it is present in a lower amount than needed.
Mole ratio of Y and [tex]XY_2[/tex] = 1:1
Equivalent mole of [tex]XY_2[/tex] = 0.12 moles
Molar mass of [tex]XY_2[/tex] = 24 + (35x2) = 94 g/mol
Mass of 0.12 moles of [tex]XY_2[/tex] = 0.12 x 94 = 11.28 grams
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The decomposition of N2O5 in a solution of carbon tetrachloride occurs as shown in the balanced chemical equation below:
2N2O5 (aq) → 4NO2 (aq) + O2 (aq)
This reaction is a first-order process with a rate constant of 4.82 x 10-3 s-1. If the initial concentration of N2O5 is 0.150 M, how much N2O5 will remain after 300.0 seconds?
a. 0.0353 M
b. 0.0553 M
c. 0.0762 M
d. 5.00 x 10-4 M
e. 0.104 M
Therefore, after 300.0 seconds, approximately 0.0553 M of N₂O₅ will remain. The correct answer is option b: 0.0553 M.
To determine how much N2O5 will remain after 300.0 seconds, we can use the first-order rate equation:
ln(N₂O₅t/N₂O₅₀) = -kt
Where N₂O₅t is the concentration of N₂O₅ at time t, N₂O₅₀ is the initial concentration of N₂O₅, k is the rate constant, and t is the time.
Substituting the given values:
N₂O₅t = N₂O₅₀ ₓ e^(-kt)
N₂O₅t = 0.150 M * e^(-4.82 x 10⁻³ s⁻¹ ˣ 300.0 s)
N₂O₅t ≈ 0.0553 M
Therefore, after 300.0 seconds, approximately 0.0553 M of N₂O₅ will remain.
The correct answer is option b: 0.0553 M.
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Jess is baking a cake. Part of the recipe has Jess mix butter and water. He notices that the two substances don't mix. He is confused because water and butter are both covalent compounds. Explain why the butter and water are NOT mixing in the bowl.
Answer:
butter and water don't mix because water is polar and butter is nonpolar
Explanation:
for them to be able to mix they would need to be both polar or both nonpolar.
HELP MEEEEEEE PLSSS!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!1 As distance increases between a rocket ship and the ground, gravitational force remains the same decreases increases pushes less
Answer:
decreases
Explanation:
Gravirational force is directly proportional to the mass and inversely proportional to the distance.(Newton's law of gravitation)
NOTE: This is a multi-part question. Once an answer is submitted, you will be unable to return to this part Let S be a set with n elements and let a and b be distinct elements of S. How many relations Rare there on S such that 2 no ordered pair in R has aas its first element or bas its second element (You must provide an answer before moving to the next part) 2(n=1)2 2n2 2n2-2no 2(n+1)2.
The number of such relations will be 2n - 2. Hence, the correct option is 2n - 2.
a and b are distinct elements of S. We need to find out how many relations R are there on S such that no ordered pair in R has a as its first element or b as its second element.So, the number of relations R on S such that no ordered pair in R has a as its first element or b as its second element is:2n - 2Note: There are n2 ordered pairs in S × S and out of them, n pairs have the first element a and n pairs have the second element b. These n + n ordered pairs must not be present in R, reducing the number of ordered pairs that may or may not be present in R by 2n. Therefore, the number of such relations will be 2n - 2. Hence, the correct option is 2n - 2.
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PLEASE HELP 20 PTS
what is the percent by volume of isopropyl alcohol in a solution that contains 24 mL of isopropyl alcohol in 1.1 L of water?
Answer:
[tex]2.18\%[/tex]
Explanation:
Volume of isopropyl alcohol = 24 mL
Volume of water = 1.1 L
Percentage of isopropyl alcohol is given by
[tex]\dfrac{\text{Volume of isopropyl alcohol}}{\text{Volume of isopropyl alcohol+Volume of water}}\times 100\\= \dfrac{24\times 10^{-3}}{1.1+2.4\times 10^{-3}}\times 100\\ =2.18\%[/tex]
The percent by volume of isopropyl alcohol in the given solution is [tex]2.18\%[/tex].
A buildup of charges in an object is called
Answer:
Static Electricity
Explanation:
Answer:
static electricity
Explanation:
given that the ksp value for mgso3 is 5.5×10−21, if the concentration of mg2 in solution is 8.9×10−11 m, the concentration of so2−3 must exceed _____ to generate a precipitate.
After considering the given data we conclude that the concentration of [tex]SO_3^2^-[/tex]must exceed [tex]6.18*10^{-11} M[/tex] to generate a precipitate of [tex]MgSO_3[/tex].
To describe the concentration of [tex]SO_3^{2-}[/tex]required to generate a precipitate of [tex]MgSO_3[/tex], we can apply the following steps:
State the balanced chemical equation for the dissolution of [tex]MgSO_3[/tex] in water.
[tex]MgSO_3(s)--- > Mg_2+(aq) + SO_3^{2-} (aq)[/tex]
Write the equation for the solubility product constant, Ksp, for [tex]MgSO_3[/tex].
[tex]Ksp = [Mg^{2+} ][SO3^{2-} ][/tex]
Stage the given concentration of [tex]Mg^{2+}[/tex] into the expression for Ksp.
[tex]Ksp = (8.9*10^{-11} M)(x)[/tex]
Here,
x = concentration of [tex]SO_3^{2-}[/tex]required to reach the saturation point and generate a precipitate.
Stage the given value of Ksp into the expression for Ksp.
Evaluate for x.
[tex]x = Ksp/[Mg^{2+} ] = (5.5*10^{-21})/(8.9*10^{-11} M) = 6.18*10^{-11 }M[/tex]
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what is the applications of electrophilic aromatic substitution reactions
Electrophilic aromatic substitution reactions have various applications in organic chemistry. They are commonly used to introduce functional groups onto aromatic rings, synthesize pharmaceuticals, produce dyes, and create complex organic molecules.
In organic chemistry, electrophilic aromatic substitution reactions are crucial tools for attaching new functional groups to aromatic rings. In these reactions, an electrophile replaces a hydrogen atom on an aromatic molecule. The end output can be used in a variety of different sectors.
Pharmaceutical synthesis is one area in which electrophilic aromatic substitution is used. Chemists can change the solubility, reactivity, and bioavailability of medicinal compounds by selectively adding functional groups to aromatic rings. This enables the creation of fresh medication candidates or the advancement of current ones.
The manufacture of dyes is an additional use. Due to their conjugated systems, aromatic compounds with particular functional groups can display bright hues. Colorful dyes used in textiles, inks, and other industries are produced through the introduction of chromophores onto aromatic rings using electrophilic aromatic substitution processes.
Additionally, it is essential for the synthesis of complex organic compounds to undergo electrophilic aromatic substitution processes. Chemists can create complex chemical structures with particular functions by carefully swapping various locations on an aromatic ring. This makes it possible to synthesize natural substances, sophisticated compounds, and materials with specific qualities.
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cells in animals and plants use the ___ that plants put in the air
Answer:
oxygen
Explanation:
plants and animals use oxygen
I need help please!!
Answer:
BECAUSE OF DENSITY
Explanation:
Answer:
It's DENSITY
Explanation:
YOURE WELCOME
Nitrogen is used to keep food frozen during transportation.
Which properties make it suitable for this?
Answer:
Gaseous nitrogen has unique chemical and physical properties that make it suitable for use in food processing. Nitrogen is inert which means it will not react with prepared food materials, which can alter their aromas or flavors. Also, gaseous nitrogen will effectively displace oxygen minimizing oxidation and the growth of microorganisms that cause foods to lose their freshness and deteriorate faster.
Explanation:
Source: https://www.generon.com/using-nitrogen-gas-in-food-packaging/
"Because it deflects oxygen, nitrogen is just a common gas for food packing." Because oxygen will carry moisture, this is critical. Bacteria use oxygen to grow and survive on organic matter. Bacteria find it much harder to develop while as much oxygen as possible is removed.
What is food packing?Food packaging is the process of packaging food. A package provides security, resistance to manipulation, and particular physical, chemical, and even biological requirements. Food packaging may include a nutrition label and other information about the product being sold.
What is bacteria?Bacteria are commonly found, mostly free-living organisms with one biological cell. They belong to the prokaryotic organisms category. Bacteria, which have been typically a few micrometers long, were one of the first living species to originate on Earth and may be found in practically every ecosystem.
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Which of the isomeric alcohols having the molecular formula C6H14OC6H14O are chiral? Which are achiral?
1-hexanol, 2-hexanol, and 3-hexanol are chiral because they possess a chiral center. 2-methylpentanol is achiral because it lacks a chiral center.
To determine which isomeric alcohols with the molecular formula C₆H₁₄O are chiral and which are achiral, we need to examine their structural features, specifically the presence or absence of a chiral center.
A chiral center is a carbon atom bonded to four different substituents, resulting in non-superimposable mirror images. If a molecule has a chiral center, it is chiral; otherwise, it is achiral.
Let's examine the structural isomers of C₆H₁₄O
1-Hexanol (CH₃(CH₂)₄OH)
This molecule contains a chiral center at the carbon atom bonded to the hydroxyl group (OH). Since it has four different substituents (CH₃, CH₂, CH₂, and H), 1-hexanol is chiral.
2-Hexanol (CH₃CH₂CH(OH)CH₂CH₃)
This molecule also contains a chiral center at the carbon atom bonded to the hydroxyl group (OH). It has four different substituents (CH₃, CH₂, CH₂, and CH₃), making 2-hexanol chiral.
3-Hexanol (CH₃CH₂CH₂(OH)CH₂CH₃)
Similarly, this molecule contains a chiral center at the carbon atom bonded to the hydroxyl group (OH). It has four different substituents (CH₃, CH₂, CH₂, and CH₃), making 3-hexanol chiral.
2-Methylpentanol (CH₃CH(CH₃)CH₂CH₂OH)
In this molecule, there is no chiral center present since the carbon atom bonded to the hydroxyl group (OH) is also bonded to two identical methyl groups (CH₃). Therefore, 2-methylpentanol is achiral.
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What types of elements [metals/nonmetals] are found in each of the compounds?
Not a simple answer please
Explanation:
List of All Elements That Are Nonmetals
Hydrogen (sometimes)
Carbon.
Nitrogen.
Oxygen.
Phosphorus.
Sulfur.
Metals:-
Gold.
Silver.
Iron.
Copper.
Nickel.
Aluminum.
Mercury( Liquid metal)
Titanium.
Fluorine.
how to obtain pure aluminium oxide from sodium aluminate. pls help.
Answer:
By Bayer process.
Explanation:
In the Bayer process, bauxite ore is heated in a pressure vessel along with a sodium hydroxide solution (caustic soda) at a temperature of 150 to 200 °C. At these temperatures, the aluminium is dissolved as sodium aluminate (primarily [Al(OH)4]−) in an extraction process.
calculate the ph of a solution that is 0.16 m nh3 and 0.22 m nh4cl kb = 1.79x10-5
We can use the concentration of OH- to calculate the pH of the solution. pOH = -log [OH-]= -log (5.87 × 10^-4)= 3.23pH + pOH = 14pH = 14 - 3.23= 10.77. Therefore, the pH of the solution is 10.77.
To calculate the pH of a solution that is 0.16 M NH3 and 0.22 M NH4Cl, we need to use the Kb expression of NH3.Kb = [NH4+][OH-]/[NH3]. The reaction between NH3 and H2O produces NH4+ and OH-.NH3 + H2O ⇌ NH4+ + OH-In this reaction, one NH3 molecule produces one NH4+ ion and one OH- ion, so the concentration of OH- will be equal to the concentration of NH4+.
Therefore,[NH4+] = 0.22 M[OH-] = 0.22 M. We know that the concentration of NH3 is 0.16 M. To calculate the concentration of OH-, we can use the Kb expression. Kb = [NH4+][OH-]/[NH3]1.79 × 10^-5 = (0.22) (0.22)/0.16[OH-] = 5.87 × 10^-4 M. Now, we can use the concentration of OH- to calculate the pH of the solution. pOH = -log [OH-]= -log (5.87 × 10^-4)= 3.23pH + pOH = 14pH = 14 - 3.23= 10.77. Therefore, the pH of the solution is 10.77.
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living things are classified into groups based on similar characteristics which of the following best represents how plants are classified
A. vertebrates and invertebrates
B.Vascular and nonvascular
C. Angiosperms and Gymnosperms
D.Producer, Consumer, and Decomposer
Pretty sure the answer is D.
Most of the world’s energy comes from what three sources?
These energy sources are called ______________fuels and they are _____________________ resources.
Answers:
Most of the world’s energy comes from what three sources?
Oil, coal, and gas.
These energy sources are called fossil fuels and they are non-renewable resources.
Fuel type: oil
How it's formed: from the remains of ancient marine organisms
Its uses: transportation, industrial power, heating and lighting, lubricants, petrochemical industry, and use of by-products
Fule type: coal
How it's formed: when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial
Its uses: electricity generation, metal production, cement production, chemical production, gasification, and other industrial uses
Fuel type: gas
How it's formed: decomposed organic matter mixed with mud, silt, and sand on the seafloor
Its uses: heating & cooling buildings, cooking foods, fueling vehicles, and electricity generation
Which of Graphs 1 correctly represents the relationship between the pressure and Kelvin temperature of a gas?
Answer:
B
Explanation:
Pressure is directly proportional to temperature
The graph correctly showing the pressure - temperature relationship is figure B. Temperature and pressure is in direct proportionality.
What is Gay- Lussacs law?According to Gay-Lussacs law, at constant volume of gases, the pressure of a gas is directly proportional to the temperature. Thus we can write it as:
P/T = a constant.
Gay-Lussacs law is supportive of kinetic molecular theory. As per kinetic theory of gases, as the temperature increases, kinetic energy of particles increases results in forceful collisions of energetic particles to the wall of container and in between them.
Therefore, the temperature - pressure graph will show a linear relationship. The figure B represents a linear curve and hence it shows the correct relation.
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show that the rydberg equation and the bohr equation are virtually the same.
In short, the Rydberg equation and the Bohr equation are two different forms of the same fundamental relationship, describing the behavior of energy levels and wavelengths in hydrogen or hydrogen-like systems.
What is Rydberg Equation ?
The Rydberg equation is an empirical relationship equation expressed by Balmer and Rydberg.
The Rydberg equation and the Bohr equation are closely related and can be considered different forms of the same mathematical expression. Let's explore them and compare their similarities.
Rydberg equation:
The Rydberg equation is an empirical formula that describes the wavelengths of spectral lines emitted or absorbed by hydrogen or hydrogen species. Is given:
1/λ = R* (1/n₁2 - 1/n₂2)
where λ is the wavelength of emitted or absorbed light, R is the Rydberg constant, and n1 and n₂ are integers representing the principal quantum numbers of the respective energy levels.
Bohr equation:
Bohr's equation, derived from Bohr's model of the hydrogen atom, relates the energy levels of an electron in a hydrogen-like atom to its principal quantum number. Is given:
E = -13.6 eV/n2
where E is the energy of the electron, -13.6 eV is the ionization energy of hydrogen, and n is the principal quantum number.
Now let's compare the two equations:
1/λ = R * (1/n₁2 - 1/n₂2) (Rydberg equation)
E = -13.6 eV/n² (Bohr equation)
We can observe that the Bohr equation gives the energy of the electron in terms of the principal quantum number, while the Rydberg equation gives the wavelength of light emitted or absorbed in terms of the principal quantum numbers.
We can use the relationship between energy and wavelength to make the connection between these two equations:
E = h*c/A
where h is Planck's constant and c is the speed of light.
Combining this relation with the Bohr equation, we have:
-13.6 eV / n² = h * c / λ
Rearranging the equation:
1/λ = (-13.6 eV / n²) / (h * c)
By comparing this equation with the Rydberg equation, we can see that the term (-13.6 eV / n²) / (h * c) is equivalent to the Rydberg constant R. Therefore, we can rewrite the equation as:
1/λ = R* (1/n₁2 - 1/n₂2)
This shows that the Rydberg equation and the Bohr equation are practically the same, just expressed in slightly different forms. The Rydberg constant R in the Rydberg equation includes the constant terms such as the ionization energy, Planck's constant, and the speed of light present in the Bohr equation.
In short, the Rydberg equation and the Bohr equation are two different forms of the same fundamental relationship, describing the behavior of energy levels and wavelengths in hydrogen or hydrogen-like systems.
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Do bananas have seeds?
Answer:
no they dont
Explanation:
in the circular flow diagram, what do firms provide to product markets?
In the circular flow diagram, firms provide goods and services to product markets.
A circular flow diagram is a simplified economic model that demonstrates how money, goods, and services flow between households and firms in an economy. This diagram is divided into two markets: the product market and the factor market. The factor market deals with inputs such as labor, capital, and raw materials, while the product market deals with outputs such as goods and services.What do firms provide to product markets?Firms are companies or businesses that generate goods or services. In the circular flow diagram, firms produce goods and services that are sold in the product market. Firms sell products to product markets. This process generates revenue for the firms, which they utilize to pay for inputs such as labor and raw materials.
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My teacher didn’t explain this. Please Help Me!!
Due to their low melting points nitrogen oxygen and helium are examples of which type of matter when at room
temperatures?
A. Gas
B.liquid
C.Plasma
D. Solid
molecular iodine, i2(g), dissociates into iodine atoms at 625 kwith a first-order rate constant of 0.271 s-1. (a) what is thehalf-life for this reaction? (b) if you start with 0.050 m i2 atthis temperature, how much will remain after 5.12 s assumingthat the iodine atoms do not recombine to form i2?
The half-life for this reaction is approximately 2.56 seconds.
Approximately 0.014 M of I₂ will remain after 5.12 s, assuming no recombination of iodine atoms to form I₂.
(a) The half-life of a first-order reaction can be calculated using the equation:
t₁/₂ = (0.693) / k
Given that the rate constant (k) is 0.271 s⁻¹, we can substitute this value into the equation:
t₁/₂ = (0.693) / 0.271 = 2.56 s
(b) To determine the remaining amount of I₂ after 5.12 s, we can use the first-order integrated rate equation:
[tex][A] = [A_{0} ]* e^{(-kt)}[/tex]
Where [A] is the concentration at time t, [A₀] is the initial concentration, k is the rate constant, and e is the base of natural logarithm.
Given [A₀] = 0.050 M, k = 0.271 s⁻¹, and t = 5.12 s, we can calculate:
[A] = 0.050 * e^(-0.271 * 5.12)
[A] = 0.050 * e^(-1.387)
[A] = 0.014 M
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If the pressure in the gas tank of the dipper was set very high, the ideal Gas law breaks
down.
Why is this happening?
a) Argon reacts with the walls of the steel vessel at high pressure
b) The molecules would clump together in the center and invalidate the law
c) A steady measurement could not be made as the gas would leak out too quickly
d) The volume occupied by the molecules themselves is no longer negligible
Answer: d) The volume occupied by the molecules themselves is no longer negligible. This most be the answer because a, b and c don't make any sense at all.
Explanation:
The volume occupied by the molecules themselves is no longer negligible. Hence, option D is correct.
What is an ideal gas equation?The ideal gas law (PV = nRT) relates the macroscopic properties of ideal gases. An ideal gas is a gas in which the particles (a) do not attract or repel one another and (b) take up no space (have no volume).
The ideal gas law fails at low temperature and high pressure because the volume occupied by the gas is quite small, so the inter-molecular distance between the molecules decreases.
Hence, the volume occupied by the molecules themselves is no longer negligible.
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calculate the enthalpy change δh for the reaction: 2so2(s) o2(g)→2so3(g)
From 250.0 g of [tex]SO_{2}[/tex], approximately -772.44 kJ of heat is produced, and approximately 24.21 g of [tex]SO_{3}[/tex] are produced when the observed enthalpy change is -75.0 kJ.
To calculate the heat produced from a given amount of [tex]SO_{2}[/tex]and the grams of [tex]SO_{3}[/tex] produced when the observed enthalpy change is given, we need to use the stoichiometry and molar masses of the compounds involved.
First, let's calculate the moles of [tex]SO_{2}[/tex]present in 250.0 g:
Molar mass of [tex]SO_{2}[/tex]= 32.07 g/mol + 32.07 g/mol = 64.14 g/mol
Moles of [tex]SO_{2}[/tex]= Mass of [tex]SO_{2}[/tex]/ Molar mass of [tex]SO_{2}[/tex]
= 250.0 g / 64.14 g/mol
≈ 3.897 mol
Using the stoichiometry of the balanced equation, we can determine the moles of [tex]SO_{3}[/tex]produced:
From the balanced equation: 2 mol [tex]SO_{2}[/tex] → 2 mol [tex]SO_{3}[/tex]
So, 3.897 mol [tex]SO_{2}[/tex]→ (3.897 mol [tex]SO_{3}[/tex]/ 2 mol [tex]SO_{2}[/tex]) = 1.9485 mol [tex]SO_{3}[/tex]
Next, let's calculate the heat produced using the given enthalpy change:
Heat produced = Moles of [tex]SO_{2}[/tex]* ΔH
Heat produced = 3.897 mol [tex]SO_{2}[/tex]* (-198.2 kJ/mol)
≈ -772.44 kJ
Therefore, approximately -772.44 kJ of heat are produced from 250.0 g of [tex]SO_{2}[/tex].
Finally, let's calculate the grams of [tex]SO_{3}[/tex]produced when the observed enthalpy change is -75.0 kJ:
Given ΔH = -75.0 kJ
Moles of [tex]SO_{3}[/tex]= ΔH / ΔH for the balanced equation
= -75.0 kJ / (-198.2 kJ/mol)
≈ 0.3782 mol
Using the molar mass of [tex]SO_{3}[/tex]:
Molar mass of [tex]SO_{3}[/tex] = 32.07 g/mol + 16.00 g/mol + 16.00 g/mol = 64.07 g/mol
Grams of [tex]SO_{3}[/tex]= Moles of [tex]SO_{3}[/tex]* Molar mass of [tex]SO_{3}[/tex]
= 0.3782 mol * 64.07 g/mol
≈ 24.21 g
Therefore, approximately 24.21 g of are produced when the observed enthalpy change is -75.0 kJ.
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The complete question is:
Given a thermochemical equation: 2SO2 (g) + O2 (g) --> 2SO3 (g), ΔH=-198.2 kJ . How many kJ of heat are made from 250.0 g SO2? . How many grams of SO3 (g) are produced when the observed enthalpy change is -75.0 kJ? Report all answers to 3 significant figures and include signs (where appropriate) and units.